BS EN 71-10-2005 Safety of toys.Organic chemical compounds. Sample preparation and extraction.pdf
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1、BRITISH STANDARD BS EN? 71-10:2005 Safety of toys Part 10: Organic chemical? compounds Sample preparation and extraction The European Standard EN 71-10:2005 has the status of a British Standard ICS 97.200.50 BS EN 71-10:2005 This British Standard was published under the authority of the Standards Po
2、licy and Strategy Committee on 12 January 2006 BSI 12 January 2006 ISBN 0 580 46782 1 National foreword This British Standard is the official English language version of ? EN 71-10:2005. The UK participation in its preparation was entrusted by Technical Committee CW/15, Safety of toys, to Subcommitt
3、ee CW/15/-/4, Chemical requirements, which has the responsibility to: A list of organizations represented on this subcommittee can be obtained on request to its secretary. Cross-references The British Standards which implement international or European publications referred to in this document may b
4、e found in the BSI Catalogue under the section entitled International Standards Correspondence Index, or by using the Search facility of the BSI Electronic Catalogue or of British Standards Online. This publication does not purport to include all the necessary provisions of a contract. Users are res
5、ponsible for its correct application. Compliance with a British Standard does not of itself confer immunity from legal obligations. aid enquirers to understand the text; present to the responsible international/European committee any enquiries on the interpretation, or proposals for change, and keep
6、 UK interests informed; monitor related international and European developments and promulgate them in the UK. Summary of pages This document comprises a front cover, an inside front cover, the EN title page, pages 2 to 25 and a back cover. The BSI copyright notice displayed in this document indicat
7、es when the document was last issued. Amendments issued since publication Amd. No. DateComments ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? EN 71-10:2005 (E) 2 Contentspage Foreword 3 Introduction4 1Scope.5 2Normative references .5 3Terms and definitions.5 4Requir
8、ements (see B.6)6 5Sample preparation.9 6Migration Sampling and extraction.9 6.1Simulant (see B.7).9 6.2Apparatus9 6.3Sampling9 6.4Extraction (see B.8).10 7Inhalation Sampling, extraction and analysis10 7.1First-action method for solvents10 7.2Final-action method for solvents.10 8Specific sampling a
9、nd extraction procedures10 8.1Textiles Flame retardants, colourants and primary aromatic amines10 8.2Leather Colourants, primary aromatic amines and preservatives.11 8.3Wood Colourants, primary aromatic amines and wood preservatives13 8.4Paper Colourants and primary aromatic amines.14 8.5Aqueous liq
10、uids - Colourants, primary aromatic amines and preservatives.14 8.6Solid toy materials intended to leave a trace - Colourants and primary aromatic amines16 8.7Modelling clay, play clay and similar - Colourants, primary aromatic amines and preservatives.16 8.8Balloon-making compounds Colourants and p
11、rimary aromatic amines.17 8.9Imitation tattoos with adhesive - Colourants, primary aromatic amines and preservatives.18 Annex A (normative) First-action method for colourants and primary aromatic amines20 Annex B (informative) Rationale22 Annex ZA (informative) Relationship between this European Sta
12、ndard and the Essential Requirements of EU Directive 88/378/EEC24 Bibliography.25 EN 71-10:2005 (E) 3 Foreword This European Standard (EN 71-10:2005) has been prepared by Technical Committee CEN/TC 52 Safety of Toys, the secretariat of which is held by DS. This European Standard shall be given the s
13、tatus of a national standard, either by publication of an identical text or by endorsement, at the latest by June 2006, and conflicting national standards shall be withdrawn at the latest by June 2006. This European Standard has been prepared under a mandate given to CEN by the European Commission a
14、nd the European Free Trade Association, and supports essential requirements of EU Directive(s). For relationship with EU Directive(s), see informative Annex ZA, which is an integral part of this European Standard. This European Standard constitutes part 10 of the European Standard on Safety of Toys.
15、 This part should be read in conjunction with parts 9 and 11. This European Standard defines the sample preparation and extraction procedures used to address potential exposure to organic compounds from ingestion, mouthing, inhalation, skin contact with solids and skin and eye contact with liquids.
16、According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Li
17、thuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. EN 71-10:2005 (E) 4 Introduction The European Standard EN 71 for safety of toys consists of the following parts: Part 1: Mechanical and physical properties Part 2: Fl
18、ammability Part 3: Migration of certain elements Part 4: Experimental sets for chemistry and related activities Part 5: Chemical toys (sets) other than experimental sets Part 6: Graphical symbols for age warning labelling Part 7: Finger paints Requirements and test methods Part 8: Swings, slides and
19、 similar activity toys for indoor and outdoor family domestic use Part 9: Organic chemical compounds Requirements Part 10: Organic chemical compounds Sample preparation and extraction Part 11: Organic chemical compounds Methods of analysis The standards EN 71-9, EN 71-10 and EN 71-11 were mandated b
20、y the European Commission (M/229) to address the risks presented by organic compounds in toys by taking into account the potential exposure and toxicological effects of those substances considered to present the greatest risk to health. This European Standard specifies the procedures for preparing a
21、nd extracting samples of toy materials prior to analysis by the methods described in EN 71-11. This part should be read in conjunction with EN 71-9, which contains requirements for certain organic compounds in toys, and EN 71-11, which specifies methods of analysis. This European Standard takes into
22、 account the opinion of the Toxicology Section of the Scientific Advisory Committee published in 1992 (EUR 13976), which recommended that certain groups of chemical compounds used in toys and toy materials need to be given special attention. In drafting this European Standard CEN/TC 52 has considere
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