BS-EN-71-11-2005.pdf
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1、BRITISH STANDARD BS EN 71-11:2005 Safety of toys Part 11: Organic chemical compounds Methods of analysis The European Standard EN 71-11:2005 has the status of a British Standard ICS 97.200.50 ? BS EN 71-11:2005 This British Standard was published under the authority of the Standards Policy and Strat
2、egy Committee on 22 November 2005 BSI 22 November 2005 ISBN 0 580 46391 5 National foreword This British Standard is the official English language version of EN 71-11:2005. The UK participation in its preparation was entrusted to Technical Committee CW/15, Safety of toys, which has the responsibilit
3、y to: aid enquirers to understand the text; present to the responsible international/European committee any enquiries on the interpretation, or proposals for change, and keep UK interests informed; monitor related international and European developments and promulgate them in the UK. A list of organ
4、izations represented on this committee can be obtained on request to its secretary. Cross-references The British Standards which implement international or European publications referred to in this document may be found in the BSI Catalogue under the section entitled “International Standards Corresp
5、ondence Index”, or by using the “Search” facility of the BSI Electronic Catalogue or of British Standards Online. This publication does not purport to include all the necessary provisions of a contract. Users are responsible for its correct application. Compliance with a British Standard does not of
6、 itself confer immunity from legal obligations. Summary of pages This document comprises a front cover, an inside front cover, the EN title page, pages 2 to 69 and a back cover. The BSI copyright notice displayed in this document indicates when the document was last issued. Amendments issued since p
7、ublication Amd. No. DateComments EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 71-11 November 2005 ICS 97.200.50 English Version Safety of toys - Part 11: Organic chemical compounds - Methods of analysis Scurit des jouets - Partie 11 : Composs chimiques organiques dans les jouets - Mthodes da
8、nalyse Sicherheit von Spielzeug - Teil 11: Organisch-chemische Verbindungen - Analysenverfahren This European Standard was approved by CEN on 27 June 2005. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the s
9、tatus of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the Central Secretariat or to any CEN member. This European Standard exists in three official versions (English, French, German).
10、A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the Central Secretariat has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Cyprus, Czech Republic, Denmark,
11、 Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISC
12、HES KOMITEE FR NORMUNG Management Centre: rue de Stassart, 36 B-1050 Brussels 2005 CENAll rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 71-11:2005: E EN 71-11:2005 (E) 2 Contents Page Foreword 3 Introduction4 1 Scope.5 2 Normative refere
13、nces .5 3 Terms and definitions.5 4 Environmental, health and safety precautions.6 5 Methods of analysis6 5.1 General 6 5.2 Flame retardants.6 5.3 Colourants.9 5.4 Primary aromatic amines15 5.5 Monomers and solvents.19 5.6 Wood preservatives37 5.7 Preservatives.41 5.8 Plasticisers44 Annex A (informa
14、tive) Methods of analysis for volatile solvents .48 Annex B (informative) Validation of test methods .65 Annex C (informative) Colourants conformational analysis 66 Annex ZA (informative) Clauses of this European Standard addressing essential requirements or other provisions of EU Directives68 Bibli
15、ography.69 EN 71-11:2005 (E) 3 Foreword This European Standard (EN 71-11:2005) has been prepared by Technical Committee CEN/TC 52 “Safety of Toys”, the secretariat of which is held by DS. This European Standard shall be given the status of a national standard, either by publication of an identical t
16、ext or by endorsement, at the latest by May 2006, and conflicting national standards shall be withdrawn at the latest by May 2006. This European Standard has been prepared under a mandate given to CEN by the European Commission and the European Free Trade Association, and supports essential requirem
17、ents of EU Directive(s). For relationship with EU Directive(s), see informative Annex ZA, which is an integral part of this European Standard. This European Standard constitutes part 11 of the European Standard on Safety of Toys. This part should be read in conjunction with parts 9 and 10. According
18、 to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania,
19、Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. EN 71-11:2005 (E) 4 Introduction The European Standard EN 71 for “safety of toys” consists of the following parts: Part 1: Mechanical and physical properties Part 2: Flammabil
20、ity Part 3: Migration of certain elements Part 4: Experimental sets for chemistry and related activities Part 5: Chemical toys (sets) other than experimental sets Part 6: Graphical symbols for age warning labelling Part 7: Finger paints Requirements and test methods Part 8: Swings, slides and simila
21、r activity toys for indoor and outdoor family domestic use Part 9: Organic chemical compounds Requirements Part 10: Organic chemical compounds Sample preparation and extraction Part 11: Organic chemical compounds Methods of analysis The European Standards EN 71-9, EN 71-10 and EN 71-11 were mandated
22、 by the European Commission (M/229) to address the risks presented by organic chemical compounds in toys by taking into account the potential exposure and toxicological effects of those substances considered to present the greatest risk to health. This European Standard specifies methods of analysis
23、 to enable assessment of compliance with the chemical requirements specified in EN 71-9 when toy and toy material extracts have been prepared according to the sampling procedures in EN 71-10. This part on methods of analysis should be read in conjunction with EN 71-9, which contains requirements for
24、 certain organic chemical compounds in toys, and EN 71-10, which describes sample preparation and extraction procedures. This European Standard takes into account the opinion of the Toxicology Section of the Scientific Advisory Committee published in 1992 (EUR 13976), which recommended that certain
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