BS EN 1392-2006 皮革和制鞋材料用胶粘剂.溶剂胶和分散胶粘剂.特定条件下测量粘结强度的试验方法.pdf

BRITISH STANDARD BS EN 1392:2006 Adhesives for leather and footwear materials Solvent-based and dispersion adhesives Testing of bond strength under specified conditions The European Standard EN 1392:2006 has the status of a British Standard ICS 61.060; 83.180 Ô·½»²-»¼ ݱ°§æ ˲·ª»®-·¬§ ±º Ó¿²½¸»-¬»®ô ˲·ª»®-·¬§ ±º Ó¿²½¸»-¬»®ô îíñðíñîðïð ððæíêô ˲½±²¬®±´´»¼ ݱ°§ô ø½÷ ÞÍ× BS EN 1392:2006 This British Standard was published under the authority of the Standards Policy and Strategy Committee on 30 June 2006 © BSI 2006 ISBN 0 580 48603 6 National foreword This British Standard is the official English language version of EN 1392:2006. This document, together with BS EN 15062:2006 supersedes BS EN 1392:1998 which is withdrawn. The UK participation in its preparation was entrusted to Technical Committee PRI/52, Adhesives, which has the responsibility to: aid enquirers to understand the text; present to the responsible international/European committee any enquiries on the interpretation, or proposals for change, and keep UK interests informed; monitor related international and European developments and promulgate them in the UK. A list of organizations represented on this committee can be obtained on request to its secretary. Cross-references The British Standards which implement international or European publications referred to in this document may be found in the BSI Catalogue under the section entitled “International Standards Correspondence Index”, or by using the “Search” facility of the BSI Electronic Catalogue or of British Standards Online. This publication does not purport to include all the necessary provisions of a contract. Users are responsible for its correct application. Compliance with a British Standard does not of itself confer immunity from legal obligations. Summary of pages This document comprises a front cover, an inside front cover, the EN title page, pages 2 to 16, an inside back cover and a back cover. The BSI copyright notice displayed in this document indicates when the document was last issued. Amendments issued since publication Amd. No. DateComments Ô·½»²-»¼ ݱ°§æ ˲·ª»®-·¬§ ±º Ó¿²½¸»-¬»®ô ˲·ª»®-·¬§ ±º Ó¿²½¸»-¬»®ô îíñðíñîðïð ððæíêô ˲½±²¬®±´´»¼ ݱ°§ô ø½÷ ÞÍ× EUROPEAN STANDARD NORME EUROPÉENNE EUROPÄISCHE NORM EN 1392 May 2006 ICS 61.060; 83.180 Supersedes EN 1392:1998 English Version Adhesives for leather and footwear materials - Solvent-based and dispersion adhesives - Testing of bond strength under specified conditions Adhésifs pour cuir et matériaux de la chaussure - Adhésifs à base de solvant ou à dispersion- Méthodes d'essai pour mesurer la résistance de collage dans certaines conditions spécifiées Klebstoffe für Leder und Schuhwerkstoffe - Lösemittel- und Dispersionsklebstoffe - Prüfung der Festigkeit von Klebungen unter festgelegten Bedingungen This European Standard was approved by CEN on 13 April 2006. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the Central Secretariat or to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the Central Secretariat has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMITÉ EUROPÉEN DE NORMALISATION EUROPÄISCHES KOMITEE FÜR NORMUNG Management Centre: rue de Stassart, 36 B-1050 Brussels © 2006 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 1392:2006: E Ô·½»²-»¼ ݱ°§æ ˲·ª»®-·¬§ ±º Ó¿²½¸»-¬»®ô ˲·ª»®-·¬§ ±º Ó¿²½¸»-¬»®ô îíñðíñîðïð ððæíêô ˲½±²¬®±´´»¼ ݱ°§ô ø½÷ ÞÍ× EN 1392:2006 (E) 2 Contents Page Foreword3 1 Scope4 2 Normative references4 3 Terms and definitions .4 4 Principle4 5 Test methods5 Ô·½»²-»¼ ݱ°§æ ˲·ª»®-·¬§ ±º Ó¿²½¸»-¬»®ô ˲·ª»®-·¬§ ±º Ó¿²½¸»-¬»®ô îíñðíñîðïð ððæíêô ˲½±²¬®±´´»¼ ݱ°§ô ø½÷ ÞÍ× EN 1392:2006 (E) 3 Foreword This document (EN 1392:2006) has been prepared by Technical Committee CEN/TC 193 “Adhesives”, the secretariat of which is held by AENOR. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by November 2006, and conflicting national standards shall be withdrawn at the latest by November 2006. This document, together with EN 15062, supersedes EN 1392:1998. According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. Safety statement Persons using this document should be familiar with the normal laboratory practice, in principle. This document does not purport to address all of the safety problems, if any, associated with its use. It is the responsibility of the user to establish appropriate safety and health practices and to ensure compliance with any regulatory conditions. Ô·½»²-»¼ ݱ°§æ ˲·ª»®-·¬§ ±º Ó¿²½¸»-¬»®ô ˲·ª»®-·¬§ ±º Ó¿²½¸»-¬»®ô îíñðíñîðïð ððæíêô ˲½±²¬®±´´»¼ ݱ°§ô ø½÷ ÞÍ× EN 1392:2006 (E) 4 1 Scope This European Standard specifies the testing of some strength properties of bonds of leather and footwear materials, in stuck-on assemblies using solvent-based and dispersion adhesives, under different conditions. These can be chosen taking into account the different stresses that such bonds are subjected to, depending on the type of footwear. 2 Normative references The following referenced documents are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. EN 923:2005, Adhesives Terms and definitions EN 1067, Adhesives Examination and preparation of samples for testing EN 12961, Adhesives for leather and footwear materials Determination of optimum activation temperatures and maximum activation life of solvent-based and dispersion adhesives EN 15307:2005, Adhesives for leather and footwear materials Sole-upper bonds - Minimum strength requirements EN ISO 868, Plastics and ebonite Determination of indentation hardness by means of a durometer (Shore hardness) (ISO 868:2003) EN ISO 7500-1, Metallic materials - Verification of static uniaxial testing machines - Part 1: Tension/compression testing machines - Verification and calibration of the force-measuring system (ISO 7500-1:2004) EN ISO 10365, Adhesives Designation of main failure patterns (ISO 10365:1992) EN ISO 15605, Adhesives Sampling (ISO 15605:2000) ISO 554, Standard atmospheres for conditioning and/or testing Specifications ISO 2602, Statistical interpretation of test results Estimation of the mean Confidence interval 3 Terms and definitions For the purposes of this document, the terms and definitions given in EN 923:2005 and the following apply. 3.1 leather tanned animal skin, usually free of hair 3.2 footwear materials natural and synthetic materials which are suitable for footwear manufacture or repair and have adequate wear properties as upper or soling material 3.3 adhesives for leather and footwear materials adhesives which are intended to produce firm and durable bonds of leather and footwear materials 4 Principle The surface of the leather or the footwear material used is treated specifically to the nature of the material. Then strips of specified length and width are cut from the treated material. Ô·½»²-»¼ ݱ°§æ ˲·ª»®-·¬§ ±º Ó¿²½¸»-¬»®ô ˲·ª»®-·¬§ ±º Ó¿²½¸»-¬»®ô îíñðíñîðïð ððæíêô ˲½±²¬®±´´»¼ ݱ°§ô ø½÷ ÞÍ× EN 1392:2006 (E) 5 Two of these strips or one strip of the above mentioned material and one strip of a suitable different material are bonded by an adhesive to test pieces of specified form. The test pieces are stored under specified conditions and their bond strength is determined under specified conditions. 5 Test methods 5.1 Types of tests 5.1.1 Peel tests at (23 ± 2) °C See 5.4.2 5.1.2 Peel test under constant load and at a constant elevated temperature (“creep test“) See 5.4.3 5.2 Adhesives and materials 5.2.1 Footwear adhesive Identify the adhesive used completely in the test report, in particular note name and/or designation, manufacturer, date of manufacture/supply and/or lot number, main polymer, type (solvent-based or dispersion) and colour. For two-part adhesives identify the nature of the crosslinking agent and the mixing ratio of the components. Record this adhesive identification in the test report. Some one or two part reference footwear test adhesives with specific properties have been developed for research, development and quality certification purposes (see EN 15307:2005, Annex A). Record the designation, source and date of supply of the reference test adhesive, if used, in the test report. 5.2.2 Leather and Footwear materials Completely identify the footwear material(s) used in the test report. Record name and/or designation, manufacturer, date of manufacture/supply, type of leather or of footwear material, e.g. soling or upper material. For leathers list colour, thickness and type of tannage (if known), for rubber and plastic materials colour, polymer base and Shore-hardness according to EN ISO 868. Include this identification of the material in the test report. Some reference footwear test materials with specified properties have been developed for research, development and quality certification purposes (see EN 15307:2005, Annex A). Record the designation, source and date of supply of the reference footwear test materials, if used, in the test report. 5.3 Apparatus and reagents 5.3.1 General The items required will depend on the types of materials used: 5.3.2 Cutting knife sharp knife, for cutting test pieces according to 5.6.2. The angle between the inner and outer cutting surface shall be approximately 20° Ô·½»²-»¼ ݱ°§æ ˲·ª»®-·¬§ ±º Ó¿²½¸»-¬»®ô ˲·ª»®-·¬§ ±º Ó¿²½¸»-¬»®ô îíñðíñîðïð ððæíêô ˲½±²¬®±´´»¼ ݱ°§ô ø½÷ ÞÍ× EN 1392:2006 (E) 6 5.3.3 Splitting machine for splitting outsole leather; 5.3.4 Roughing machine consists of a rotary wire brush with a wire diameter between 0,1 mm and 0,4 mm. The linear speed of revolution shall be between 10 m/s and 25 m/s; 5.3.5 Scouring machine with a drum covered with emery paper or emery cloth of 60 grit size and a linear speed of revolution of between 10 m/s and 20 m/s; 5.3.6 Hard felt disc made from wool for removing thin PVC coats from PVC upper materials; 5.3.7 Brush for dust removing hand or mechanical device for removing the dust from strips of material after roughing or scouring; 5.3.8 Material for solvent wiping suitable lintfree fabric or cotton wool. The material for solvent wiping must remain unaffected by the solvent used. Size about 150 mm x 150 mm; 5.3.9 Solvents ethyl acetate (acetic acid ethyl ester) acetone or light petroleum, boiling range 80 °C to 110 °C; 5.3.10 Halogenation agent, solvent borne, 1- or 2-part for treating rubber surfaces; 5.3.11 Brush for halogenation hard and soft with a non-metallic bristle holder for halogenation; bristle length about (20 ± 5) mm; 5.3.12 Adhesive applicator e.g. brush, roller, coating machine etc. for uniform coating of the adhesive under test; 5.3.13 Heat activator for heating adhesive coats to the required temperature; 5.3.14 Equipment for measurement of temperature thermocouple, infrared thermometer, thermoindicator papers or melting powders for measuring the temperature of activated adhesive coats; 5.3.15 Pressing device providing a precise and even pressure of up to 0,6 MPa over the whole of the surface to be bonded; Ô·½»²-»¼ ݱ°§æ ˲·ª»®-·¬§ ±º Ó¿²½¸»-¬»®ô ˲·ª»®-·¬§ ±º Ó¿²½¸»-¬»®ô îíñðíñîðïð ððæíêô ˲½±²¬®±´´»¼ ݱ°§ô ø½÷ ÞÍ× EN 1392:2006 (E) 7 5.3.16 Tensile testing machine according to EN ISO 7500-1 for measuring maximum separation forces up to 10 kN and suitable force measurement ranges. The tensile testing machine shall record automatically the separation forces determined, and to be adjustable to a constant rate of traverse of (100 ± 10) mm/min during the test. 5.3.17 Oven with forced ventilation capable of storing test pieces at (50 ± 2) °C. 5.3.18 Warm air cabinet with forced ventilation capable of maintaining the contents at temperatures between 40 °C and 100 °C with tolerances of ± 2 °C and suitable for testing test pieces in accordance with 5.4.The test cabinet shall be fitted with a window and devices for clamping five test pieces. These devices shall consist of upper clamps fixed on a metal bar in the cabinet and lower clamps which shall have means for attaching weights which pass through cylindrical holes in the base of the cabinet. All lower clamps shall be of the same mass and capable of being loaded with weights so that total loads applied by the individual clamps are 0,5 kg, 1,0 kg, 1,5 kg, 2,0 kg and 2,5 kg. 5.3.19 Weights with a tolerance of ± 1 % for applying loads of 0,5 kg, 1,0 kg, 1,5 kg, 2,0 kg and 2,5 kg, including the weight of a clamp to the test pieces. 5.4 Form of test pieces 5.4.1 General Prepare from the leather and footwear materials strips as specified in 5.6.2. If a material, does not allow the cutting of strips of the required dimensions, smaller and/or shorter strips may be used for preparing test pieces of the specified form, providing that their dimensions and overlap are recorded in the test report. 5.4.2 Peel test at (23 ± 2) °C Two strips of material up to (100 ± 2) mm long and (30 ± 0,5) mm wide are bonded to cover each other over a length of at least (60 ± 2) mm (see Figure 1). Ô·½»²-»¼ ݱ°§æ ˲·ª»®-·¬§ ±º Ó¿²½¸»-¬»®ô ˲·ª»®-·¬§ ±º Ó¿²½¸»-¬»®ô îíñðíñîðïð ððæíêô ˲½±²¬®±´´»¼ ݱ°§ô ø½÷ ÞÍ× EN 1392:2006 (E) 8 Dimensions in mm Key 1 length of the bond in millimetres Figure 1 Form and dimensions of test pieces for the peel tests 5.4.3 Peel test under constant load and at a constant elevated temperature (“creep test“) Use the same test pieces as specified in 5.4.2 5.5 Number of test pieces Prepare for every test and storage condition chosen at least three peel test pieces, at least 15 peel test pieces for the preliminary creep tests necessary for assessing the test temperature